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Army scientists develop dual-polymer 3D-printing tech: ABS and PC in all one

By Thomas Brading, U.S. Army

U.S. Army scientists are on the brink of a pioneering additive-manufacturing technology to help Soldiers quickly swap out broken plastic components with durable 3D-printed replacements, says a top Army researcher.

In the past, troops have either lugged replacement parts around or ordered them from warehouses thousands of miles away, only to wait weeks for them to arrive.

But with dual-polymer 3D-printed parts -- developed by scientists at the U.S. Army Combat Capabilities Development Command Army Research Laboratory, or ARL -- Soldiers could be a few clicks away from swapping out broken pieces and heading back to the fight within hours.

Dr. Eric Wetzel demonstrates dual-polymer filaments at the U.S. Army Research Lab on Feb. 10, 2020.

 

 

"We're crossing a threshold where low-cost, easy-to-operate and maintain printers will be proliferated on the battlefield -- and able to produce engineering parts of very good quality with short turnaround times," said Dr. Eric Wetzel, ARL's research area leader for Soldier materials.

"In order to do that, we need printing technologies that can print parts that are accurate geometrically and have mechanical properties that are sufficiently robust to survive conditions in battle," he added.

The printing technology comes on the heels of Secretary of the Army Ryan McCarthy pushing an advanced manufacturing policy last October, intended to enhance supply chains in the field.

Until this point, 3D-printing technologies that produce mechanically robust parts have required printers and print technologies that are not suitable for austere environments, while the printers suitable for austere environments produced poor-quality parts, Wetzel said.

That's where the ARL scientists come in. For the last few years, they have delved into this issue, Wetzel said. For the first time, ARL scientists have developed a cutting-edge filament capable of being used in off-the-shelf, low-cost 3D printers to produce mechanically strong, battlefield-ready parts.

"By summer, we hope to have samples of the filament distributed to Army transition partners," Wetzel added. Based on their feedback, ARL could ramp up production -- with help from industry partners -- and have it in the hands of Soldiers within the calendar year.

The dual-polymer technology
"Conventional polymer filaments for 3D printing are made up of a single polymer," Wetzel said. "Our innovation is that we've combined two different polymers into a single filament, providing a unique combination of characteristics useful for printing and building strength."

The dual-polymer filament combines acrylonitrile butadiene styrene, or ABS, with polycarbonate, or PC. A critical design feature of the filament is that the ABS and PC phases are not simply mixed together, a common approach for creating blended polymers. Instead, a special die-less thermal drawing process developed by ARL is used to create an ABS filament with a star-shaped PC core. Once coupled, the filament is used as feedstock in a desktop fused-filament fabrication, or FFF, printer to create 3D prints with a heavy-duty ABS/PC meso?structure.

The dual-polymer filament developed by Army scientists at the U.S. Research Lab in Aberdeen, MD, is made of acrylonitrile butadiene styrene (ABS) coupled with a star?shaped polycarbonate (PC) core.

 

 

 

 

FFF printers work with a heated nozzle that emits thin layers of melted plastic, similar to molten glass. The filament is deposited onto a print bed, one layer on top of another until it forms the 3D-printed part. In order to fabricate a unique part, the nozzle, print bed, or both move while the hot plastic streams down.

The two polymers found in the new filament technology have distinct melting temperatures, Wetzel said.

After the solid bodies are initially printed, they are put in an oven to build strength. During this annealing process, the deposited material layers fuse together while maintaining their geometry and form. This stability is caused by the higher temperature resistance of the built-in framework.

"The second polymer holds the shape like a skeleton while the rest of it is melting and bonding together," Wetzel said. "Through a series of filament design trials, we were able to identify that the star-shaped PC core provided a superior combination of part toughness and stability compared to other arrangements of ABS and PC in the filament."

VIDEO: U.S. Army scientist's invention leads to fused filament fabrication downrange.

Current filaments -- traditionally consisting of a single thermoplastic -- produce parts that are brittle and weak, and would deform excessively during the annealing process, he said.

"We focused in on what can we do to improve those mechanical properties," he added. "We wrote a series of papers getting very fundamentally down to the details of exactly why conventional single-polymer parts are not sufficient, what's happening in the physics of the polymer -- really at a molecular level -- that prevents conventional printed polymer parts from meeting these requirements."

The legacy thermoplastic deposits like a hot glue gun, he said. As the layers build, they don't stick very well to the previous layer because by the time the second layer adds, the first one is cooled off.

"So, you're not melting the layers together, you're just solidifying material on top of one another, and they never really bond between layers," Wetzel said. "Our technology is an approach that allows us to use these conventional desktop printers, but then apply post-processing to dramatically improve the toughness and strength between layers."

"Manufacturing at the point of need provides some exciting possibilities," Wetzel said. "In the future, we can imagine Soldiers deployed overseas collaborating with engineers in the United States, allowing new hardware concepts to be designed and then sent as digital files to be converted into physical prototypes that the Soldiers can use the same day. This paradigm shift could allow us to innovate at a much higher speed, and be keenly responsive to the ever-changing battlefield."

Published April 2020

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